In a large bowl, whisk together dark rye flour, bread flour, cocoa powder, caraway seeds, instant yeast, fine salt, and sugar until evenly combined.
In a separate bowl, combine warm water, molasses, apple cider vinegar, and vegetable oil. Stir until the molasses is fully dissolved. Check that the liquid is around 110°F (43°C).
Pour wet ingredients into dry ingredients and stir with a wooden spoon until a thick, sticky dough forms. It will look and feel more like a thick batter than conventional bread dough. Do not add extra flour.
Grease a 9x5-inch loaf pan thoroughly. Transfer the sticky dough into the pan, using a wet spatula or wet hands to smooth the top evenly. Cover loosely with plastic wrap or a kitchen towel.
Let dough rise at room temperature for 1.5 to 2 hours. The rise will be subtle; look for the top to rise slightly above the rim or level with it, and the surface to look puffy.
About 20 minutes before the rise is complete, preheat the oven to 375°F (190°C) with a rack in the lower third. Verify the temperature with an oven thermometer.
Just before baking, use a sharp knife or bread lame to make one shallow score down the center of the loaf, about 1/4 inch (6mm) deep. Sprinkle with caraway or sesame seeds if desired, pressing them in lightly.
Bake at 375°F (190°C) for 35 minutes uncovered. Tent the top with aluminum foil, reduce oven temperature to 325°F (165°C), and continue baking for 40 to 50 minutes more. Total bake time is 75-85 minutes.
Bread is done when a thermometer inserted into the center reads 200-205°F (93-96°C) or when the loaf sounds hollow when tapped on the bottom. Remove from the oven and cool in the pan for 10 minutes.
Turn the loaf out onto a wire rack and cool completely, at least 2 to 3 hours, before slicing. This allows the crumb to firm up and flavors to develop fully.